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《Ceramics International》2021,47(21):30358-30366
Stereolithography-based 3D printing is a promising method to produce complex shapes from piezoceramic materials. In this study, LCD-SLA 3D printing was used to create lead-free piezoceramics based on barium titanate (BaTiO3, BT). Three types of BT powders (micron, submicron and nanoscale) were tested in LCD-SLA 3D printing, and a technique for the preparation of a ceramic slurry suitable for LCD-SLA printing has been developed. Using TGA-DSC analysis, the thermal debinding parameters to obtain crack-free samples were determined, followed by further sintering and the study of the piezoelectric properties (εr = 1965, d33 = 200 pC/N, tan = 1,7 %). The results of the study demonstrate high potential for the production of complex piezoceramic elements that can be used in aviation, in particular, aviation radio equipment; in the marine industry for transceiver modules of hydroacoustic antennas; and in the nuclear industry for pressure control sensors in the steam–water path. 相似文献
3.
Chenfei Shi Yuling Su Jinjin Guo Jiangying Zhang Gaoshang Gong Huiyun Hu Yongqiang Wang 《Ceramics International》2021,47(8):10887-10892
In this paper, the crystal structure, vacancy defect, local electron density and magnetic properties of Gd1-xCaxCrO3 (0 ≤ x ≤ 0.3) polycrystalline samples were investigated systematically. The crystal structural analyses show that all the samples are orthorhombic phase and a structural distortion happens around x = 0.3. Due to the formation of Cr4+ ions, both the lattice constant and the Cr–O bond length decrease. The results of positron annihilation spectrum reveals that the vacancy defect concentration increases and the local electron structure changes with the introduction of Ca2+ ions. The field-cooled (FC) and zero-field cooled (ZFC) curves of Gd1-xCaxCrO3 samples measured under H = 100 Oe exhibits negative magnetization characteristics due to the interaction between Gd3+ and Cr3+ ions, and the magnetism can be affected by the structural distortion. 相似文献
4.
Dr. Daniel Feder Dr. Siti H. Mohd-Pahmi Dr. Waleed M. Hussein Prof. Luke W. Guddat Prof. Ross P. McGeary Prof. Gerhard Schenk 《ChemMedChem》2021,16(21):3342-3359
Metallohydrolases form a large group of enzymes that have fundamental importance in a broad range of biological functions. Among them, the purple acid phosphatases (PAPs) have gained attention due to their crucial role in the acquisition and use of phosphate by plants and also as a promising target for novel treatments of bone-related disorders and cancer. To date, no crystal structure of a mammalian PAP with drug-like molecules bound near the active site is available. Herein, we used a fragment-based design approach using structures of a mammalian PAP in complex with the MaybridgeTM fragment CC063346, the amino acid L-glutamine and the buffer molecule HEPES, as well as various solvent molecules to guide the design of highly potent and efficient mammalian PAP inhibitors. These inhibitors have improved aqueous solubility when compared to the clinically most promising PAP inhibitors available to date. Furthermore, drug-like fragments bound in newly discovered binding sites mapped out additional scaffolds for further inhibitor discovery, as well as scaffolds for the design of inhibitors with novel modes of action. 相似文献
5.
某电力公司变电站用铝合金设备线夹在运行过程发生批次开裂事故,通过宏观观察、断口分析、化学成分分析、力学性能测试、冷冻模拟试验等方法,对设备线夹的开裂原因和开裂机理进行了分析。结果表明:设备线夹焊缝存在焊接缺陷,导致焊缝强度下降;设备线夹接线管底部存在积水空间,寒冷天气下积水结冰,体积膨胀,使焊缝承受设计工况外的负载而过载开裂,造成了线夹开裂。 相似文献
6.
为了研究温度分布对于管阵列结构中的声透射特性的影响,以核电站的实际工况为背景,构建了不同的温度场以及周期性变化的非均匀温度场,利用有限元方法进行数值模拟。结果表明:(1)温度分布会改变管阵列声透射频谱的“禁带”宽度以及中心频率位置。在同一介质中,温度变化对频率较高位置的影响大于频率较低的位置。(2)在同样为10℃的温度差下,当水的平均声速为1 653 m·s-1、饱和水蒸气的平均声速为522.5 m·s-1时,介质为水时的禁带宽度及中心频率位置变化较大,即声速大的介质的频谱对于温度的变化更敏感。(3)当温度差在10℃以内,在周期性变化的非均匀温度场和与均匀温度场中管阵列声透射特性在第一中心频率23 996.1 Hz之前,两频谱差别很小,在第一禁带之后会出现明显区别。该研究成果对完善核电站应用的声学检测提供了理论基础。 相似文献
7.
《International Journal of Hydrogen Energy》2022,47(97):41097-41110
The present work was focused on the corrosion properties and contact resistance behavior of poly(orthophenlyenediamine) (PoPD) coating on 316L SS bipolar plates. To reduce the corrosion rate and increase the interfacial conductivity of 316L SS bipolar plates, PoPD coating was deposited using an electropolymerization technique by the various monomer concentration of orthophenlyenediamine (oPD) on its surface. The presence of 1, 2, 4, 5- tetra substituted benzene nuclei of phenazine units in the polymer coating was confirmed by infrared spectroscopy. X-ray photoelectron spectroscopy analysis has confirmed the (%) of chemical composition in PoPD coating. The results of scanning electron microscopy analysis revealed that the uniform and compact coating with complete cover on 316L SS. The corrosion properties were investigated in 0.5 M H2SO4 and 2 ppm HF solution at 80 °C. The polarization test results showed that the PoPD coating reduced the corrosion current density both in the PEMFC anode and cathode environments. The charge transfer resistance values were in the order of 316L SS ? 0.02 M PoPD ? 0.06 M PoPD ? 0.04 M PoPD. A very low interfacial contact resistance and good adhesion strength was observed for 0.04 M PoPD coating. The higher contact angle of 0.04 M PoPD coating explained the hydrophobic property and more benefit of water management in the PEMFC environment. The results of the analysis of total metal ion releases clearly explained that the low level of metal ions released for 0.04 M PoPD coating. The overall studies revealed the PoPD coating with optimized 0.04 M oPD concentration showed best performance and provided more anodic protection to 316L SS bipolar plates. 相似文献
8.
《International Journal of Hydrogen Energy》2022,47(2):971-983
The synthesized novel metal oxides YxCeyRuzO4 (x = 1.5, y = 0.84, z = 0.04) which was produced by the sol-gel method was used as a support for Cu active metal on the surface of a microchannel plate reactor in the methanol steam reforming (MSR) process. The prepared catalysts were characterized by X-ray powder diffraction (XRD), BET surface area analysis (SBET), energy-dispersive X-ray analysis (EDX), field-emission scanning electron microscopy (FE-SEM), X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), temperature-programmed desorption (NH3-TPD), and temperature-programmed reduction (H2-TPR). High methanol conversion (99.5%) and H2 selectivity (98.7%) and low CO selectivity (1.4%) were achieved for Cu/YxCeyRuzO4 coated microchannel reactor at 250 °C. FE-SEM images and TGA curve of the spent catalyst displayed no coke formation on the surface of the catalyst after 32 h on stream at 300 °C. The low reduction temperature of Cu, high BET surface area, and high pore volume of the catalyst are considered imperative factors that cause a better dispersion of copper on the Y1.5Ce0.84Ru0.04O4 support. 相似文献
9.
This study aims to improve the performances of a solar still single slope using metal oxide nanofluid (Al2O3–water, Cu2O–water, and TiO2–water). The numerical study was carried out for the climatic conditions of Agadir, Morocco, with different concentrations of nanofluids inside a basin equipped with an absorber plate with two different absorptivities. The numerical study is based on thermal balance equations applied on different solar system components and solved using the Runge Kutta method. The numerical model is validated by comparing our results with the literature available data. A comparison study of the effect of these nanofluids on solar still productivity is done. The results show that the productivity of the solar still using nanoparticles Cu2O, TiO2, and Al2O3 are 7.38, 7.1, and 7.064 kg m−2 day−1, respectively. It is obtained that the maximum efficiency of the solar still is found to be 55.27% by using cuprous oxide nanoparticles. Furthermore, an enhancement in solar still productivity of 6.36%, 19.54%, and 33.25% is obtained by dispersing 1%, 3%, and 5% volume fraction of Cu2O nanoparticles in pure water, respectively compared to the conventional solar. Moreover, the impact of the absorptivity of the absorber plate on the solar still effectiveness is investigated. Two types of coatings are considered to change the absorber plate absorptivity. The results indicate that the efficiencies of the solar system are 58.81% and 51.77% using an absorber plate with 0.95 and 0.85 of absorptivity, respectively. 相似文献
10.